Alright, it seems you are not a ham-radio operator, otherwise you'd knew what a handheld or walkie talkie is.
So you can not transmit on 437MHz to check the lnb.
Ok, 40ish MHz an 25ish MHz is good! Means the TCXO in V3D is working and you have output, just not disciplined by GPS.
Now, who modified the LNB? Was it someone who can check it ?
Feeding the UNMODIFIED lnb with 24(25) MHz external will not work. It will use it's internal crystal.
But you should see signals on 144MHz IF YOU jumper V3D to 25MHz and listen on 144MHz. The output of the unmod lnb is 739 MHz and will be converted to 144MHz if V3D is set to 25MHz , otherwise , when it is set for 24MHz it expects 1129MHz to convert it to 144MHz, so if you still feed in 739MHz, the output WILL NOT BE 144MHz. Here's why: Modern lnb's use a 25MHz crystal, multiply the frequency by 390 to get 9750MHz . 10490MHz-9750=740MHz . In order to receive the Amateur TV-Transponder with consumer electronics satellite receivers, which cannot receive 740MHz, one must use a frequency they can handle. So if you feed 24MHz instead of 25, the result is 10490-9360 = 1130MHz, which they can handle. So i think you are close to receiving with your unmodified lnb->V3D->Pluto on 144MHz if you set V3D to 25MHz. Try it. Just don't bridge NB IN and WB out, but hook the unmod lnb to NB IN. If that works, the culprit might be the modified lnb. So once you have a working modified lnb, next step is to find out why gps doesn't work.